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Bis(dibenzylideneacetone) Palladium | C34H20O2Pd | CAS 32005-36-0

  • Product Name: Bis(dibenzylideneacetone)palladium
  • CAS: 32005-36-0
  • MF: C34H20O2Pd
  • MW:566.95
  • EINECS: 608-691-6
  • Mol File: 32005-36-0.mol
  • Origin: China

    Property

    Melting point: 150°C
    Storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
    Solubility: Chloroform (Slightly)
    Form: Fine Powder
    Color: Red-brown to black
    Water Solubility: insoluble

    Application

    Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) was employed as catalyst in the following studies:
    Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands.
    Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand.
    Allylation of stabilized anions.Cross coupling of allyl, alkenyl and aryl halides with organostannanes.
    Cross coupling of vinyl halides with alkenyl zinc species.Carbonylation of alkenyl and aryl halides.
    Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones.

    Package And Storage

    Package: 
    25kg/carton drum or as your requirements.
    Remark: Chemical composition and size can be optimized by the customers' requirements固体16gs固体2ys0

     Storage:
    Separated from ammonium nitrate and potassium chlorate. Dry.Keep container tightly closed in a dry and well-ventilated place. Hygroscopic.

    Safety Protection

    Precautions for safe handling
    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

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